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Coordination Chemistry Mock Tests

16 questions available

Coordination Chemistry Mock Test 1

Questions: 16

नमूना प्रश्न

GATE Chemistry
The cis-isomer of [Co(en)₂Cl₂]⁺ (where en = ethylenediamine) is chiral and optically active. The trans-isomer is:
A Chiral and optically active
B Achiral and optically inactive
C Chiral but optically inactive
D Achiral but optically active
GATE Chemistry
The Tanabe-Sugano diagram for a d⁸ octahedral complex shows three spin-allowed transitions. The ground state term symbol for a d⁸ octahedral complex is:
A ³T₁g
B ³A₂g
C ¹A₁g
D ³T₂g
GATE Chemistry
The number of unpaired electrons in the hexafluorocobaltate(III) ion, [CoF₆]³⁻, is:
A 0
B 1
C 4
D 6
GATE Chemistry
Which of the following coordination complexes exhibits the strongest Jahn-Teller distortion in an octahedral geometry? (Consider the electronic configurations and the degeneracy of the ground state in each case.)
A [CuF₆]⁴⁻ (Cu²⁺, d⁹)
B [Ti(H₂O)₆]³⁺ (Ti³⁺, d¹)
C [MnF₆]³⁻ (Mn³⁺, d⁴, high-spin)
D [CoF₆]³⁻ (Co³⁺, d⁶, high-spin)
NEET Chemistry
Which of the following is the correct order of crystal field splitting energy (Δ₀) for the given complexes?
A [Co(NH₃)₆]³⁺ < [Co(CN)₆]³⁻ < [Co(F)₆]³⁻
B [Co(F)₆]³⁻ < [Co(NH₃)₆]³⁺ < [Co(CN)₆]³⁻
C [Co(CN)₆]³⁻ < [Co(NH₃)₆]³⁺ < [Co(F)₆]³⁻
D [Co(NH₃)₆]³⁺ < [Co(F)₆]³⁻ < [Co(CN)₆]³⁻
NEET Chemistry
Which of the following is the correct order of magnetic moments for [Fe(H₂O)₆]²⁺, [Fe(CN)₆]⁴⁻, and [Fe(CN)₆]³⁻?
A [Fe(H₂O)₆]²⁺ > [Fe(CN)₆]³⁻ > [Fe(CN)₆]⁴⁻
B [Fe(CN)₆]⁴⁻ > [Fe(CN)₆]³⁻ > [Fe(H₂O)₆]²⁺
C [Fe(CN)₆]³⁻ > [Fe(H₂O)₆]²⁺ > [Fe(CN)₆]⁴⁻
D [Fe(H₂O)₆]²⁺ > [Fe(CN)₆]⁴⁻ > [Fe(CN)₆]³⁻
GATE Chemistry
Using Tanabe-Sugano diagrams for d² octahedral complexes, the ground state term symbol for a d² ion in an octahedral field is ³T₁g(F). As the ligand field strength (Δ₀ or 10Dq) increases, the first spin-allowed electronic transition corresponds to which excited state? (The Tanabe-Sugano diagram for d² shows the energy levels as a function of Δ₀/B, where B is the Racah parameter.)
A ³T₂g(F)
B ³A₂g(F)
C ³T₁g(P)
D ¹E_g(G)
NEET Chemistry
Which of the following is the correct order of magnetic moments for the given complexes? (All involve Fe ions)
A [Fe(CN)₆]⁴⁻ < [Fe(H₂O)₆]²⁺ < [Fe(CN)₆]³⁻
B [Fe(H₂O)₆]²⁺ < [Fe(CN)₆]⁴⁻ < [Fe(CN)₆]³⁻
C [Fe(CN)₆]³⁻ < [Fe(CN)₆]⁴⁻ < [Fe(H₂O)₆]²⁺
D [Fe(CN)₆]⁴⁻ < [Fe(CN)₆]³⁻ < [Fe(H₂O)₆]²⁺

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